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Impact of Corrosion in Water Systems: Prevention and Maintenance

Understanding Corrosion in Water Systems

Understanding Corrosion in Water Systems

Recognizing the different types of corrosion in water systems, understanding how and why they occur, and their impact on system metallurgy is important for developing a good water treatment program to control corrosion.

Once corrosion begins in a water system, it can rapidly escalate into a significant issue, leading to costly downtime, additional resource allocation, and financial losses for business owners. Globally, the costs associated with corrosion in water systems amount to billions of dollars annually. According to a study by NACE International, the global cost of corrosion across various industries, including water systems, is estimated to be around $2.5 trillion annually. 

Corrosion in Water Systems

corrosion in water infrastructure

Corrosion-induced metal loss can significantly impact the reliability and lifespan of water systems and their components, including distribution pipes and related equipment. This degradation leads to higher maintenance costs and premature equipment failure. Additionally, corrosion can impair heat transfer efficiency, cause deposit buildup, restrict water flow, and ultimately reduce system efficiency. Proactively understanding and addressing the various types of corrosion and their causes can prevent them from escalating uncontrollably.

Types of Corrosion in Water Systems

what is general corrosion

Generalized Corrosion

This corrosion occurs uniformly across a metal surface, leading to widespread material loss. While generalized corrosion often causes fouling within a water system, it is less likely to result in sudden equipment failure.

Localized Corrosion

Localized corrosion manifests as small pits or depressions on the metal surface. This type is more problematic as it can lead to significant damage. Types of localized corrosion include pitting, under-deposit corrosion, galvanic corrosion, and microbiologically influenced corrosion (MIC) caused by organisms like Pseudomonas. Localized corrosion can create cracks or breaks in the metal, potentially leading to system failures.

What is Galvanic Corrosion?

galvanic corrosion in pipes

Galvanic corrosion arises from a chemical reaction between two metals immersed in a conductive solution. This reaction essentially forms a basic battery, where one metal (the anode) corrodes while the other (the cathode) is protected.

The rate of galvanic corrosion depends on the specific metals involved. A galvanic potential chart can help predict the likelihood and rate of corrosion. To control galvanic corrosion, devices like dielectric unions are used to separate the metals. These unions break the electrical circuit, typically made from galvanized steel and lead-free brass, preventing electrolysis and subsequent corrosion. 

What is Pitting Corrosion?

pitting corrosion in pipes

Pitting corrosion is a highly unpredictable and destructive form of metallic corrosion. It occurs when specific areas of a metal surface undergo intense, localized corrosion while the majority of the surface remains unaffected.

Several factors increase the risk of pitting corrosion, including stagnant water conditions and low water flow velocity. Corrosive ions, such as chlorides, sulfates, and oxygen, further exacerbate the risk. Once a pit forms as a depression in the metal surface, the trapped liquid within the pit becomes even more corrosive, accelerating the damage.

Under-Deposit Corrosion

under deposit corrosion UDC
Pipelines corrosion during water supply process - Scientific Figure on ResearchGate. Available from: https://www.researchgate.net/figure/Corrosion-deposits-distribution-in-the-pipe-section_fig1_325714275 [accessed 6 Aug 2024]
Under deposit corrosion (UDC) is a localized form of corrosion that occurs beneath or around deposits on metal surfaces, often found in water-carrying systems like pipelines and boilers. These deposits, which can include rust, dirt, scale, and biological matter, create microenvironments that promote corrosion by fostering oxygen concentration cells and differential aeration. The area under the deposit typically has lower oxygen levels, becoming anodic and more prone to corrosion, while the surrounding areas act as cathodic, accelerating the corrosion process. 
 
Certain metals and alloys, like aluminium, copper, and steel, which rely on oxide films for protection, are more susceptible to under-deposit corrosion. This type of corrosion is commonly found at the ends of lines, lower levels of process runs, or points in the system where water flow is slower. The most effective way to prevent under-deposit corrosion in water systems is to maintain cleanliness and keep all metal-based systems free from contamination.

Microbiologically Influenced Corrosion (MIC)

what is microbiologically influenced corrosion MIC
Microbiologically influenced corrosion (MIC) in water systems refers to any corrosion primarily caused by bacteria, including species such as Pseudomonas, sulfate-reducing bacteria, and nitrite-reducing bacteria.
 
MIC often contributes to the formation of corrosion tubercles and can influence other types of corrosion. Bacteria themselves do not directly attack the metal; rather, the corrosion results from the by-products of bacterial growth, which react with the metal. These by-products create an environment that accelerates corrosion processes, making MIC a significant concern in water systems. 

Erosion-Corrosion in Water Systems

Erosion Corrosion in Water Systems
Erosion-corrosion is the combined effect of mechanical abrasion and chemical corrosion caused by water flow in a system. Almost all metals can experience some erosion-corrosion, but soft metals, especially those relying on a passive protective layer, are particularly vulnerable.
 
Fluids containing suspended solids can exacerbate erosion-corrosion. To prevent this, it is best to address erosion-corrosion during the design stage by creating a system that maintains consistent flow speeds, considering the types of metals used, and minimizing changes in flow direction.
 
Another practical approach is to remove or limit suspended solids with a filtration system, such as a side stream filter, to reduce the risk of erosion-corrosion.

What is Tuberculation?

causes tuberculation in pipe
Tuberculation refers to the accumulation of corrosion by-products and other deposits on metal surfaces, often affecting iron components. These deposits, or tubercles, form over areas where metal has been lost due to corrosion. The composition of a tubercle depends on various factors, including the chemical makeup of the water, dissolved oxygen concentration, water flow, temperature, and corrosion rate.
 
As metal corrodes, tubercles develop and corrosion accumulates underneath. The corroded areas beneath tubercles are typically irregular and broad depressions. However, not all red or brown iron oxide deposits are tubercles; if there is no metal loss beneath these deposits, the iron might have accumulated from other parts of the water system.

Tips to Help Prevent Corrosion in Water Systems

how to prevent corrosion in water systems

Use a Water Softener

Water softeners can reduce the hardness of water by removing minerals such as calcium and magnesium, which are known to contribute to scale formation and corrosion. By softening the water, you minimize the deposition of these minerals on the surfaces of pipes and other components, thereby reducing the risk of corrosion.

Install a Corrosion Control System

Corrosion control systems involve the addition of chemicals or treatments to the water to inhibit corrosion processes. For example, inhibitors like phosphates can be added to form a protective film on the metal surfaces, while pH adjusters can balance the water chemistry to make it less corrosive. These systems are tailored to the specific needs of your water system to provide optimal protection.

Keep Your Water Temperature Low

Hot water accelerates chemical reactions, including corrosion. Keeping the water temperature as low as practical can significantly reduce the rate of corrosion. This is particularly important in systems where metals like copper and iron are present, as higher temperatures increase the solubility of oxygen and other corrosive agents, exacerbating corrosion.

Avoid Using Harsh Chemicals

Harsh chemicals such as bleach and certain acids can damage the protective oxide layers on metal surfaces, leading to increased corrosion. Instead, use milder cleaning agents that do not react aggressively with the metal components of your water system. Regular maintenance with appropriate cleaning agents can help preserve the integrity of the system.

ORAPI RECOMMENDS: 

FLEX COTE is a clear methacrylate copolymer coating designed to protect bare metal components and plastic parts from harsh environmental conditions. 
 
It offers outstanding durability, adhesion, toughness, and corrosion protection, even after prolonged exposure to high humidity, corrosive vapors, and salt spray.

Have Your Water Tested Regularly

Regular water testing is crucial to monitor the quality of your water and detect any changes that could lead to corrosion. Tests can reveal high levels of acidity, alkalinity, chlorides, or other corrosive substances. Early detection allows timely intervention, such as adjusting the water chemistry or enhancing corrosion protection measures, to prevent extensive damage.

Conclusion

Understanding corrosion in water systems is important for effective prevention and maintenance. Proactive measures like water softening, corrosion control systems, regular water testing, and maintaining appropriate water temperatures can significantly reduce maintenance costs and extend equipment lifespan. These practices help businesses mitigate financial and operational risks associated with corrosion, ensuring the longevity and efficiency of their water systems.

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